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Web whereas, flea collars, infused with active ingredients that gradually release over time, create a protective barrier around your pet's neck, offering an alternative method of flea control with considerations. These chemicals kill any fleas that try to settle. The answer is yes, but they might not be the best option for everyone. The collar slowly releases active ingredients over your pet’s. Web flea collars are one method of flea prevention that many pet owners opt for, but do they actually work? Web how does a flea collar work on a dog? The collars contain pesticides designed to kill and prevent fleas. Web the active ingredients flow from an area of high concentration and storage (the seresto ® collar) to low concentration (your pet’s hair, coat and skin). A flea collar works by releasing chemicals that spread along the pet's body through the oils on their fur and skin.